(O-Methyl dithiocarbonato-κS)triphenyltin(IV)

Fatima Javed; Saqib Ali; Wajid Shah; M. Nawaz Tahir; Hameed Ullah

doi:10.1107/S1600536813012300

(O-Methyl dithiocarbonato-κS)triphenyltin(IV)

Fatima Javed, Saqib Ali, Wajid Shah, M. Nawaz Tahir, Hameed Ullah

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, [Sn(C₆H₅)₃(C ₂H₃OS₂)], the Sn^IV atom adopts a distorted SnC₃S tetrahedral coordination geometry. A short Sn⋯O contact [2.988 (4) Å] is also present. The phenyl rings are each disordered over two sets of sites with an occupancy ratio of 0.550 (8):0.450 (8). The crystal studied was found to be a racemic twin with a twin component ratio of 0.57 (18):0.43 (18).

Original language	English (US)
Pages (from-to)	m316
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	69
Issue number	6
DOIs	https://doi.org/10.1107/S1600536813012300
Publication status	Published - Jun 2013
Externally published	Yes

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title = "(O-Methyl dithiocarbonato-κS)triphenyltin(IV)",

abstract = "In the title compound, [Sn(C6H5)3(C 2H3OS2)], the SnIV atom adopts a distorted SnC3S tetrahedral coordination geometry. A short Sn⋯O contact [2.988 (4) {\AA}] is also present. The phenyl rings are each disordered over two sets of sites with an occupancy ratio of 0.550 (8):0.450 (8). The crystal studied was found to be a racemic twin with a twin component ratio of 0.57 (18):0.43 (18).",

author = "Fatima Javed and Saqib Ali and Wajid Shah and Tahir, \{M. Nawaz\} and Hameed Ullah",

year = "2013",

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language = "English (US)",

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journal = "Acta Crystallographica Section E: Structure Reports Online",

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T1 - (O-Methyl dithiocarbonato-κS)triphenyltin(IV)

AU - Javed, Fatima

AU - Ali, Saqib

AU - Shah, Wajid

AU - Tahir, M. Nawaz

AU - Ullah, Hameed

PY - 2013/6

Y1 - 2013/6

N2 - In the title compound, [Sn(C6H5)3(C 2H3OS2)], the SnIV atom adopts a distorted SnC3S tetrahedral coordination geometry. A short Sn⋯O contact [2.988 (4) Å] is also present. The phenyl rings are each disordered over two sets of sites with an occupancy ratio of 0.550 (8):0.450 (8). The crystal studied was found to be a racemic twin with a twin component ratio of 0.57 (18):0.43 (18).

AB - In the title compound, [Sn(C6H5)3(C 2H3OS2)], the SnIV atom adopts a distorted SnC3S tetrahedral coordination geometry. A short Sn⋯O contact [2.988 (4) Å] is also present. The phenyl rings are each disordered over two sets of sites with an occupancy ratio of 0.550 (8):0.450 (8). The crystal studied was found to be a racemic twin with a twin component ratio of 0.57 (18):0.43 (18).

UR - https://www.scopus.com/pages/publications/84878709395

U2 - 10.1107/S1600536813012300

DO - 10.1107/S1600536813012300

M3 - Article

AN - SCOPUS:84878709395

SN - 1600-5368

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SP - m316

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 6

ER -

(O-Methyl dithiocarbonato-κS)triphenyltin(IV)

Abstract

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